Ionic conductivity of the Na1+xMxIIIZr2−x(PO4)3 systems (M = Al, Ga, Cr, Fe, Sc, In, Y, Yb)
Identifieur interne : 000426 ( Main/Exploration ); précédent : 000425; suivant : 000427Ionic conductivity of the Na1+xMxIIIZr2−x(PO4)3 systems (M = Al, Ga, Cr, Fe, Sc, In, Y, Yb)
Auteurs : RBID : ISTEX:10853_1990_Article_BF00582473.pdfAbstract
The existence and ionic conductivity of solid solutions Na1+xMxIIIZr2−x(PO4)3 with Nasicon-like structure have been investigated and the results compared with literature data. A limited range of solid solutions is formed with MIII = aluminium, gallium, yttrium, ytterbium, whereas a continuous series is obtained for MIII = chromium, iron, scandium, indium. The pure end member Na3ln2(PO4)3 is reported for the first time; according to powder diffraction data, it is hexagonal witha = 0.8966(1) andc = 2.2104(4) nm. The small monoclinic distortion already known for MIII = chromium, iron and scandium is restricted tox values very close to 2. Ionic conductivity measurements show that for a given value ofx, the mobility of the Na+ ions is strongly influenced both by the ionic radius and the type of electronic structure of the MIII ion. However, no simple correlation can be found.
DOI: 10.1007/BF00582473
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Tarte</name><affiliation wicri:level="1"><mods:affiliation>University of Liège, Institute of Chemistry, B-4000, Sart-Tilman par Liège, 1, Belgium</mods:affiliation><country xml:lang="fr">Belgique</country><wicri:regionArea>University of Liège, Institute of Chemistry, B-4000, Sart-Tilman par Liège, 1</wicri:regionArea><wicri:noRegion>1</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="RBID">ISTEX:10853_1990_Article_BF00582473.pdf</idno><date when="1990">1990</date><idno type="doi">10.1007/BF00582473</idno><idno type="wicri:Area/Main/Corpus">000410</idno><idno type="wicri:Area/Main/Curation">000410</idno><idno type="wicri:Area/Main/Exploration">000426</idno></publicationStmt></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="eng">The existence and ionic conductivity of solid solutions Na1+xMxIIIZr2−x(PO4)3 with Nasicon-like structure have been investigated and the results compared with literature data. A limited range of solid solutions is formed with MIII = aluminium, gallium, yttrium, ytterbium, whereas a continuous series is obtained for MIII = chromium, iron, scandium, indium. The pure end member Na3ln2(PO4)3 is reported for the first time; according to powder diffraction data, it is hexagonal witha = 0.8966(1) andc = 2.2104(4) nm. The small monoclinic distortion already known for MIII = chromium, iron and scandium is restricted tox values very close to 2. Ionic conductivity measurements show that for a given value ofx, the mobility of the Na+ ions is strongly influenced both by the ionic radius and the type of electronic structure of the MIII ion. However, no simple correlation can be found.</div></front></TEI><mods xsi:schemaLocation="http://www.loc.gov/mods/v3 file:///applis/istex/home/loadistex/home/etc/xsd/mods.xsd" version="3.4" istexId="473ee97dfde829c0de2f9dea4cbf878b9a1f1385"><titleInfo lang="eng"><title>Ionic conductivity of the Na1+xMxIIIZr2−x(PO4)3 systems (M = Al, Ga, Cr, Fe, Sc, In, Y, Yb)</title></titleInfo><name type="personal"><namePart type="given">J. M.</namePart><namePart type="family">Winand</namePart><role><roleTerm type="text">author</roleTerm></role><affiliation>University of Liège, Institute of Chemistry, B-4000, Sart-Tilman par Liège, 1, Belgium</affiliation></name><name type="personal"><namePart type="given">A.</namePart><namePart type="family">Rulmont</namePart><role><roleTerm type="text">author</roleTerm></role><affiliation>University of Liège, Institute of Chemistry, B-4000, Sart-Tilman par Liège, 1, Belgium</affiliation></name><name type="personal"><namePart type="given">P.</namePart><namePart type="family">Tarte</namePart><role><roleTerm type="text">author</roleTerm></role><affiliation>University of Liège, Institute of Chemistry, B-4000, Sart-Tilman par Liège, 1, Belgium</affiliation></name><typeOfResource>text</typeOfResource><genre>Papers</genre><genre>Original Paper</genre><originInfo><publisher>Kluwer Academic Publishers, Dordrecht</publisher><dateCreated encoding="w3cdtf">1989-05-04</dateCreated><dateCaptured encoding="w3cdtf">1989-09-29</dateCaptured><dateValid encoding="w3cdtf">2004-10-20</dateValid><copyrightDate encoding="w3cdtf">1990</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType></physicalDescription><abstract lang="eng">The existence and ionic conductivity of solid solutions Na1+xMxIIIZr2−x(PO4)3 with Nasicon-like structure have been investigated and the results compared with literature data. A limited range of solid solutions is formed with MIII = aluminium, gallium, yttrium, ytterbium, whereas a continuous series is obtained for MIII = chromium, iron, scandium, indium. The pure end member Na3ln2(PO4)3 is reported for the first time; according to powder diffraction data, it is hexagonal witha = 0.8966(1) andc = 2.2104(4) nm. The small monoclinic distortion already known for MIII = chromium, iron and scandium is restricted tox values very close to 2. Ionic conductivity measurements show that for a given value ofx, the mobility of the Na+ ions is strongly influenced both by the ionic radius and the type of electronic structure of the MIII ion. However, no simple correlation can be found.</abstract><relatedItem type="series"><titleInfo type="abbreviated"><title>J Mater Sci</title></titleInfo><titleInfo><title>Journal of Materials Science</title><partNumber>Year: 1990</partNumber><partNumber>Volume: 25</partNumber><partNumber>Number: 9</partNumber></titleInfo><genre>Archive Journal</genre><originInfo><dateIssued encoding="w3cdtf">1990-09-01</dateIssued><copyrightDate encoding="w3cdtf">1990</copyrightDate></originInfo><subject usage="primary"><topic>Chemistry</topic><topic>Polymer Sciences</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Characterization and Evaluation Materials</topic><topic>Mechanics</topic></subject><identifier type="issn">0022-2461</identifier><identifier type="issn">Electronic: 1573-4803</identifier><identifier type="matrixNumber">10853</identifier><identifier type="local">IssueArticleCount: 57</identifier><recordInfo><recordOrigin>Chapman and Hall Ltd., 1990</recordOrigin></recordInfo></relatedItem><identifier type="doi">10.1007/BF00582473</identifier><identifier type="matrixNumber">Art30</identifier><identifier type="local">BF00582473</identifier><accessCondition type="use and reproduction">MetadataGrant: OpenAccess</accessCondition><accessCondition type="use and reproduction">AbstractGrant: OpenAccess</accessCondition><accessCondition type="restriction on access">BodyPDFGrant: Restricted</accessCondition><accessCondition type="restriction on access">BodyHTMLGrant: Restricted</accessCondition><accessCondition type="restriction on access">BibliographyGrant: Restricted</accessCondition><accessCondition type="restriction on access">ESMGrant: Restricted</accessCondition><part><extent unit="pages"><start>4008</start><end>4013</end></extent></part><recordInfo><recordOrigin>Chapman and Hall Ltd., 1990</recordOrigin><recordIdentifier>10853_1990_Article_BF00582473.pdf</recordIdentifier></recordInfo></mods></record>Pour manipuler ce document sous Unix (Dilib)
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